The reference material IAEA-603 was developed to replace the quarantined reference material NBS 19 and to serve as the highest-level metrological reference material for the practical realization of the VPDB and VPDB-LSVEC δ(13C) scales and VPDB and VPDB-CO2 δ(18O) scales.
Certified values of IAEA-603
Note: For δ(13C), currently two scales exist and are in use: VPDB and VPDB-LSVEC. δ(13C) values reported on the VPDB and VPDB-LSVEC scale can differ, with maximum reported differences (VPDB minus VPDB-LSVEC) of +0.3 ‰ for materials with carbon isotope delta values around –45 ‰ and negligible difference (below current analytical combined uncertainty) at carbon isotope delta values close to zero [https://doi.org/10.1002/rcm.10018)].
End users should state the values of reference materials used to normalize isotope data following the minimum requirements established by IUPAC [https://doi.org/10.1515/pac-2021-1108] and in the case of carbon, whether they are publishing δ(13C) values on the VPDB scale or the VPDB-LSVEC scale. Users should ensure that in one calibration they only use values for reference materials assigned on one scale.